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Electrochemical Energy Reviews ›› 2019, Vol. 2 ›› Issue (3): 395-427.doi: 10.1007/s41918-019-00035-5

所属专题： Batteries

• REVIEW ARTICLE • 上一篇    下一篇

Electrode Materials for Rechargeable Zinc-Ion and Zinc-Air Batteries: Current Status and Future Perspectives

Dan Yang1,2, Huiteng Tan2, Xianhong Rui1,2, Yan Yu1,3,4   

  1. 1 Hefei National Laboratory for Physical Sciences at the Microscale, Department of Materials Science and Engineering, Key Laboratory of Materials for Energy Conversion, Chinese Academy of Sciences(CAS), University of Science and Technology of China, Hefei 230026, Anhui, China;
    2 Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China;
    3 Dalian National Laboratory for Clean Energy(DNL), Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
    4 State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei 230026, Anhui, China
  • 收稿日期:2019-01-16 修回日期:2019-02-13 出版日期:2019-09-20 发布日期:2019-09-18
  • 通讯作者: Xianhong Rui, Yan Yu E-mail:xhrui@gdut.edu.cn;yanyumse@ustc.edu.cn
  • 基金资助:
    The authors gratefully acknowledge the National Key R&D Program of China (Grant No. 2018YFB0905400), the National Natural Science Foundation of China (Grant No. 51622210, 51872277, 21606003 and 51802044), the DNL Cooperation Fund, CAS (DNL180310), the Fundamental Research Funds for Central Universities (WK3430000004) and the Opening Project of CAS Key Laboratory of Materials for Energy Conversion.

Electrode Materials for Rechargeable Zinc-Ion and Zinc-Air Batteries: Current Status and Future Perspectives

Dan Yang1,2, Huiteng Tan2, Xianhong Rui1,2, Yan Yu1,3,4   

  1. 1 Hefei National Laboratory for Physical Sciences at the Microscale, Department of Materials Science and Engineering, Key Laboratory of Materials for Energy Conversion, Chinese Academy of Sciences(CAS), University of Science and Technology of China, Hefei 230026, Anhui, China;
    2 Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China;
    3 Dalian National Laboratory for Clean Energy(DNL), Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
    4 State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei 230026, Anhui, China
  • Received:2019-01-16 Revised:2019-02-13 Online:2019-09-20 Published:2019-09-18
  • Contact: Xianhong Rui, Yan Yu E-mail:xhrui@gdut.edu.cn;yanyumse@ustc.edu.cn
  • Supported by:
    The authors gratefully acknowledge the National Key R&D Program of China (Grant No. 2018YFB0905400), the National Natural Science Foundation of China (Grant No. 51622210, 51872277, 21606003 and 51802044), the DNL Cooperation Fund, CAS (DNL180310), the Fundamental Research Funds for Central Universities (WK3430000004) and the Opening Project of CAS Key Laboratory of Materials for Energy Conversion.

摘要：

Advanced energy storage systems hold critical signifcance in satisfying the ever-increasing global demand for energy. And as a viable and efective alternative to lithium-ion batteries that dominate the current energy market, Zn-based batteries[i.e. Zn-ion batteries (ZIBs) and Zn-air batteries (ZABs)] have attracted extensive research eforts. Zn metal possesses many advantages because of its high theoretical capacity, its inexpensiveness and its good safety characteristic, and in recent years, tremendous eforts have been carried out to accelerate the development of ZIBs and ZABs with various electrode materials and electrocatalysts being proposed and investigated. In addition, with advances in characterization techniques, the underlying reaction mechanisms of these materials are also being elucidated. Therefore, this review will provide a comprehensive summary of the latest progress in various electrode materials adopted in the current ZIBs and ZABs along with corresponding mechanisms. Specifcally, Mn- and V-containing cathode materials for ZIBs and associated reaction mechanisms will be thoroughly discussed, and emerging cathodes such as Prussian blue analogues, NASICON-type nanostructures and organic compounds will be presented. In terms of ZABs, this review will discuss three major types of electrocatalysts, including noble metals, heteroatom-doped carbons and transition metal oxides/sulphides/phosphides/nitrides. In addition, as a critical factor in the performance of Zn-based batteries, challenges encountered by the current Zn anodes and strategies developed to tackle these issues will be discussed as well. Finally, a short summary including the current progress and future perspectives of ZIBs and ZABs will be provided.


Full-text：https://link.springer.com/article/10.1007/s41918-019-00035-5/fulltext.html

关键词: Zn-ion battery, Zn-air battery, Cathode material, Electrocatalyst, Zn anode

Abstract:

Advanced energy storage systems hold critical signifcance in satisfying the ever-increasing global demand for energy. And as a viable and efective alternative to lithium-ion batteries that dominate the current energy market, Zn-based batteries[i.e. Zn-ion batteries (ZIBs) and Zn-air batteries (ZABs)] have attracted extensive research eforts. Zn metal possesses many advantages because of its high theoretical capacity, its inexpensiveness and its good safety characteristic, and in recent years, tremendous eforts have been carried out to accelerate the development of ZIBs and ZABs with various electrode materials and electrocatalysts being proposed and investigated. In addition, with advances in characterization techniques, the underlying reaction mechanisms of these materials are also being elucidated. Therefore, this review will provide a comprehensive summary of the latest progress in various electrode materials adopted in the current ZIBs and ZABs along with corresponding mechanisms. Specifcally, Mn- and V-containing cathode materials for ZIBs and associated reaction mechanisms will be thoroughly discussed, and emerging cathodes such as Prussian blue analogues, NASICON-type nanostructures and organic compounds will be presented. In terms of ZABs, this review will discuss three major types of electrocatalysts, including noble metals, heteroatom-doped carbons and transition metal oxides/sulphides/phosphides/nitrides. In addition, as a critical factor in the performance of Zn-based batteries, challenges encountered by the current Zn anodes and strategies developed to tackle these issues will be discussed as well. Finally, a short summary including the current progress and future perspectives of ZIBs and ZABs will be provided.


Full-text：https://link.springer.com/article/10.1007/s41918-019-00035-5/fulltext.html

Key words: Zn-ion battery, Zn-air battery, Cathode material, Electrocatalyst, Zn anode

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