Electrochemical Energy Reviews ›› 2020, Vol. 3 ›› Issue (3): 541-580.doi: 10.1007/s41918-020-00070-7

• REVIEW ARTICLE • 上一篇    下一篇

Dealloyed nanoporous materials for rechargeable lithium batteries

Xuan Wu1,2, Guang He1, Yi Ding1   

  1. 1. Tianjin Key Laboratory of Advanced Functional Porous Materials, Institute for New Energy Materials and Low-Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, China;
    2. State Key Laboratory of Quality Research in Chinese Medicines, Macau University of Science and Technology, Taipa, Macau, China
  • 收稿日期:2020-02-27 修回日期:2020-03-28 出版日期:2020-09-20 发布日期:2020-10-19
  • 基金资助:
    This work was supported by the National Key Research and Development Program of China (2019YFA0205700), the National Natural Science Foundation of China (51602219, 51671145), the National Science Fund for Distinguished Young Scholars (51825102), the joint research fund of NSFC (51761165012) and the Macau Science and Technology Fund (FDCT, 002/2017/AFJ), and the Tianjin Municipal Science and Technology Commission (17JCYBJC42000). X.W. and G.H. contributed equally to this work.

Dealloyed nanoporous materials for rechargeable lithium batteries

Xuan Wu1,2, Guang He1, Yi Ding1   

  1. 1. Tianjin Key Laboratory of Advanced Functional Porous Materials, Institute for New Energy Materials and Low-Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, China;
    2. State Key Laboratory of Quality Research in Chinese Medicines, Macau University of Science and Technology, Taipa, Macau, China
  • Received:2020-02-27 Revised:2020-03-28 Online:2020-09-20 Published:2020-10-19
  • Supported by:
    This work was supported by the National Key Research and Development Program of China (2019YFA0205700), the National Natural Science Foundation of China (51602219, 51671145), the National Science Fund for Distinguished Young Scholars (51825102), the joint research fund of NSFC (51761165012) and the Macau Science and Technology Fund (FDCT, 002/2017/AFJ), and the Tianjin Municipal Science and Technology Commission (17JCYBJC42000). X.W. and G.H. contributed equally to this work.

摘要:

Dealloying has been recognized as a universal strategy to fabricate various functional electrode materials with open networks, nanoscale ligaments, tunable pore sizes and rich surface chemistry, all of which are very attractive characteristics for rechargeable lithium batteries. In particular, lithium ion insertion/extraction in metal anodes is naturally associated with the alloying/dealloying mechanism. The past decade has witnessed rapid growth of this research field with enormous progress. In this review article, we first summarize the recent development and microstructural regulation of dealloyed materials. Next, we focus on the rational design of nanoporous electrodes for rechargeable lithium batteries and related structure-performance correlations. Finally, some critical issues and perspectives are presented to guide the future development directions of such promising technology for high-energy batteries.


Full-text:https://link.springer.com/article/10.1007/s41918-020-00070-7https://link.springer.com/article/10.1007/s41918-020-00070-7

关键词: Dealloying, Lithium batteries, Nanoporous, Rechargeable, Electrodes

Abstract:

Dealloying has been recognized as a universal strategy to fabricate various functional electrode materials with open networks, nanoscale ligaments, tunable pore sizes and rich surface chemistry, all of which are very attractive characteristics for rechargeable lithium batteries. In particular, lithium ion insertion/extraction in metal anodes is naturally associated with the alloying/dealloying mechanism. The past decade has witnessed rapid growth of this research field with enormous progress. In this review article, we first summarize the recent development and microstructural regulation of dealloyed materials. Next, we focus on the rational design of nanoporous electrodes for rechargeable lithium batteries and related structure-performance correlations. Finally, some critical issues and perspectives are presented to guide the future development directions of such promising technology for high-energy batteries.


Full-text:

Key words: Dealloying, Lithium batteries, Nanoporous, Rechargeable, Electrodes