Electrochemical Energy Reviews ›› 2022, Vol. 5 ›› Issue (1): 187-210.doi: 10.1007/s41918-021-00107-5

• • 上一篇    

The Trade-Offs in the Design of Reversible Zinc Anodes for Secondary Alkaline Batteries

Honglin Luo1, Bin Liu2,3, Zhiwei Yang1, Yizao Wan1, Cheng Zhong2,3   

  1. 1. Institute of Advanced Materials, East China Jiaotong University, Nanchang, 330013, Jiangxi, China;
    2. Key Laboratory of Advanced Ceramics and Machining Technology(Ministry of Education), School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, China;
    3. Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, China
  • 收稿日期:2020-11-22 修回日期:2021-03-22 出版日期:2022-03-20 发布日期:2022-03-14
  • 通讯作者: Cheng Zhong,E-mail:cheng.zhong@tju.edu.cn E-mail:cheng.zhong@tju.edu.cn
  • 基金资助:
    Honglin Luo and Bin Liu contributed equally to this work. This work was supported by the Tianjin Natural Science Foundation (18JCJQJC46500), National Science Foundation for Excellent Young Scholar (No. 51722403), National Natural Science Foundation of China (No. 51771134), and National Youth Talent Support Program.

The Trade-Offs in the Design of Reversible Zinc Anodes for Secondary Alkaline Batteries

Honglin Luo1, Bin Liu2,3, Zhiwei Yang1, Yizao Wan1, Cheng Zhong2,3   

  1. 1. Institute of Advanced Materials, East China Jiaotong University, Nanchang, 330013, Jiangxi, China;
    2. Key Laboratory of Advanced Ceramics and Machining Technology(Ministry of Education), School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, China;
    3. Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, China
  • Received:2020-11-22 Revised:2021-03-22 Online:2022-03-20 Published:2022-03-14
  • Contact: Cheng Zhong,E-mail:cheng.zhong@tju.edu.cn E-mail:cheng.zhong@tju.edu.cn
  • Supported by:
    Honglin Luo and Bin Liu contributed equally to this work. This work was supported by the Tianjin Natural Science Foundation (18JCJQJC46500), National Science Foundation for Excellent Young Scholar (No. 51722403), National Natural Science Foundation of China (No. 51771134), and National Youth Talent Support Program.

摘要: Zinc-based batteries have long occupied the largest share of the primary battery market, but this advantage has not continued in the secondary battery market. This is mainly because the cycling performance of secondary zinc-based batteries is significantly limited by the poor reversibility of zinc electrodes, including the formation of zinc dendrites, electrode deformation, corrosion, and hydrogen evolution. To solve the above problems, researchers have developed many novel strategies, such as surface coating, use of electrode additives, use of electrolyte additives, and electrode structure design. However, the implementation of these strategies inevitably requires consideration of trade-offs because the core factors that limit the reversibility of zinc electrodes are not isolated but intertwined. Therefore, fully understanding the trade-offs in the zinc electrode design process is necessary to fundamentally improve the cycling performance of the zinc electrode and construct a practical secondary zinc-based battery. This perspective gives an introduction to various problems that limit the cycling of zinc electrodes and discusses the theoretical causes of these problems. The trade-offs in various typical strategies are systematically analyzed, and their positive and negative effects on performance are discussed. This work aims to provide insights for the development of highly reversible zinc anodes for practical secondary zinc-based batteries.

关键词: Aqueous batteries, Zinc anode, Zinc-based batteries, Trade-of

Abstract: Aqueous batteries|Zinc anode|Zinc-based batteries|Trade-of