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Electrochemical Energy Reviews ›› 2024, Vol. 7 ›› Issue (4): 29-.doi: 10.1007/s41918-024-00213-0

• •    下一篇

Progress of Main-Group Metal-Based Single-Atom Catalysts

Tongzhou Wang1,2, Yuhan Sun1, Genyuan Fu1, Zhiqi Jiang1, Xuerong Zheng1, Jihong Li1,2, Yida Deng1   

  1. 1. State Key Laboratory of Marine Resource Utilization in South China Sea, School of Materials Science and Engineering, Hainan University, Haikou 570228, Hainan, China;
    2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin 300071, China
  • 收稿日期:2023-01-17 修回日期:2023-09-28 出版日期:2024-12-20 发布日期:2024-12-28
  • 通讯作者: Jihong Li,E-mail:jihong_18@hainanu.edu.cn;Yida Deng,E-mail:yd_deng@hainanu.edu.cn E-mail:jihong_18@hainanu.edu.cn;yd_deng@hainanu.edu.cn
  • 基金资助:
    The work performed in China is financially supported by the National Natural Science Foundation of China (52301013,52201009 and 52231008);the Hainan Provincial Natural Science Foundation of China (223RC401);the Education Department of Hainan Province (Hnky2023ZD-2,Hnky2024ZD-2);the Starting Research Funds of the Hainan University of China[KYQD (ZR)-21105,KYQD (ZR)-23090];the Collaborative Innovation Center of Marine Science and Technology,Hainan University (XTCX2022HYC18,XTCX2022HYC22);and the Scientific and Technological Project of Yunnan Precious Metals Laboratory (YPML-2023050268).

Progress of Main-Group Metal-Based Single-Atom Catalysts

Tongzhou Wang1,2, Yuhan Sun1, Genyuan Fu1, Zhiqi Jiang1, Xuerong Zheng1, Jihong Li1,2, Yida Deng1   

  1. 1. State Key Laboratory of Marine Resource Utilization in South China Sea, School of Materials Science and Engineering, Hainan University, Haikou 570228, Hainan, China;
    2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin 300071, China
  • Received:2023-01-17 Revised:2023-09-28 Online:2024-12-20 Published:2024-12-28
  • Contact: Jihong Li,E-mail:jihong_18@hainanu.edu.cn;Yida Deng,E-mail:yd_deng@hainanu.edu.cn E-mail:jihong_18@hainanu.edu.cn;yd_deng@hainanu.edu.cn
  • Supported by:
    The work performed in China is financially supported by the National Natural Science Foundation of China (52301013,52201009 and 52231008);the Hainan Provincial Natural Science Foundation of China (223RC401);the Education Department of Hainan Province (Hnky2023ZD-2,Hnky2024ZD-2);the Starting Research Funds of the Hainan University of China[KYQD (ZR)-21105,KYQD (ZR)-23090];the Collaborative Innovation Center of Marine Science and Technology,Hainan University (XTCX2022HYC18,XTCX2022HYC22);and the Scientific and Technological Project of Yunnan Precious Metals Laboratory (YPML-2023050268).

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摘要： Single-atom catalysts (SACs) have emerged as promising materials in energy conversion and storage systems due to their maximal atom utilization, unique electronic structure, and high efficiency. Among them, main-group metal-based SACs (the s-block and p-block metals) are emerging extraordinary materials and have attracted particular interest in the past few years but are still confronted with several challenges. Initiating with a critical overview of the fundamentals and unique advantages associated with main-group metals, the review proceeds to highlight several types of main-group metal-based SACs. These include s-block metals such as Mg and Ca, and p-block metals such as In, Bi, Al, Ga, Sb, Se, and Sn. The applications of these SACs in diverse chemical energy conversion processes are thoroughly explored. Finally, to promote the future development of highly efficient main-group metal SACs, the critical challenges and prospects in this emerging field are proposed. This review presents a fresh impetus and solid platform for the rational design and synthesis of high-performance main-group metal SAC catalysts for chemical energy conversion fields.

关键词: Main group metal, Single atom catalyst, Energy conversion process, Catalytic reactions

Abstract: Single-atom catalysts (SACs) have emerged as promising materials in energy conversion and storage systems due to their maximal atom utilization, unique electronic structure, and high efficiency. Among them, main-group metal-based SACs (the s-block and p-block metals) are emerging extraordinary materials and have attracted particular interest in the past few years but are still confronted with several challenges. Initiating with a critical overview of the fundamentals and unique advantages associated with main-group metals, the review proceeds to highlight several types of main-group metal-based SACs. These include s-block metals such as Mg and Ca, and p-block metals such as In, Bi, Al, Ga, Sb, Se, and Sn. The applications of these SACs in diverse chemical energy conversion processes are thoroughly explored. Finally, to promote the future development of highly efficient main-group metal SACs, the critical challenges and prospects in this emerging field are proposed. This review presents a fresh impetus and solid platform for the rational design and synthesis of high-performance main-group metal SAC catalysts for chemical energy conversion fields.

Key words: Main group metal, Single atom catalyst, Energy conversion process, Catalytic reactions

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