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Electrochemical Energy Reviews ›› 2019, Vol. 2 ›› Issue (2): 252-276.doi: 10.1007/s41918-019-00030-w

所属专题： Other Topics

• REVIEW ARTICLE • 上一篇    下一篇

Oxygen Reduction Reactions of Fe-N-C Catalysts: Current Status and the Way Forward

Hangjia Shen1, Tiju Thomas2, Sefu Abolaji Rasaki1,4, Ali Saad1, Chun Hu3,4, Jiacheng Wang3, Minghui Yang1   

  1. 1 Solid State Functional Materials Research Laboratory, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China;
    2 Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Adyar, Chennai, Tamil Nadu 600036, India;
    3 State Key Laboratory of High Performance Ceramics and Superfne Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;
    4 University of Chinese Academy of Science, Beijing 100049, China
  • 收稿日期:2018-09-20 修回日期:2018-12-17 出版日期:2019-06-20 发布日期:2019-06-28
  • 通讯作者: Jiacheng Wang, Minghui Yang E-mail:jiacheng.wang@mail.sic.ac.cn;myang@nimte.ac.cn
  • 基金资助:
    This work is supported by the National Natural Science Foundation of China (21471147) and the National Key Research and Development Program of China (2016YFB0101200). M. Yang appreciates the support from the Ningbo 3315 program. J. Wang would like to thank the financial support from the Science and Technology Commission of Shanghai Municipality (15520720400, 16DZ2260603) and the Equipment Research Program (6140721050215). Tiju Thomas would like to thank the Indian Institute of Technology, Madras and the Department of Science and Technology (DST, Government of India) for their fnancial support in the form of grants such as the Young Scientist Scheme (YSS/2015/001712) and the Centre Grant CHY1718383DSTXTPRA and SOL1819001DSTXHOCX. Tiju Thomas would also like to thank the Ministry of Electronics & Information Technology for their support and the Centre grant ELE1819353MEITENAK (in which he is a Center member). H. Shen would like to acknowledge the contributions made by Liu Yang at the Beijing Advanced Innovation Center for Soft Matter Science and Engineering at the Beijing University of Chemical Technology.

Oxygen Reduction Reactions of Fe-N-C Catalysts: Current Status and the Way Forward

Hangjia Shen1, Tiju Thomas2, Sefu Abolaji Rasaki1,4, Ali Saad1, Chun Hu3,4, Jiacheng Wang3, Minghui Yang1   

  1. 1 Solid State Functional Materials Research Laboratory, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China;
    2 Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Adyar, Chennai, Tamil Nadu 600036, India;
    3 State Key Laboratory of High Performance Ceramics and Superfne Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;
    4 University of Chinese Academy of Science, Beijing 100049, China
  • Received:2018-09-20 Revised:2018-12-17 Online:2019-06-20 Published:2019-06-28
  • Contact: Jiacheng Wang, Minghui Yang E-mail:jiacheng.wang@mail.sic.ac.cn;myang@nimte.ac.cn
  • Supported by:
    This work is supported by the National Natural Science Foundation of China (21471147) and the National Key Research and Development Program of China (2016YFB0101200). M. Yang appreciates the support from the Ningbo 3315 program. J. Wang would like to thank the financial support from the Science and Technology Commission of Shanghai Municipality (15520720400, 16DZ2260603) and the Equipment Research Program (6140721050215). Tiju Thomas would like to thank the Indian Institute of Technology, Madras and the Department of Science and Technology (DST, Government of India) for their fnancial support in the form of grants such as the Young Scientist Scheme (YSS/2015/001712) and the Centre Grant CHY1718383DSTXTPRA and SOL1819001DSTXHOCX. Tiju Thomas would also like to thank the Ministry of Electronics & Information Technology for their support and the Centre grant ELE1819353MEITENAK (in which he is a Center member). H. Shen would like to acknowledge the contributions made by Liu Yang at the Beijing Advanced Innovation Center for Soft Matter Science and Engineering at the Beijing University of Chemical Technology.

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摘要： Currently, Fe-N-C materials are considered to be among the most important oxygen reduction reaction (ORR) catalysts, because they are potential substitutes for Pt-based catalysts and are therefore promising in the development of non-noble metal-based catalysts. However, challenges such as electron transfer kinetics still exist and need to be improved upon. From a chemical stand point, improvements can be made through the better understanding of mechanisms in Fe-N-C-based ORR catalysis along with a deeper understanding of the chemical origin of active sites on Fe-N-C catalyst surfaces. Based on these, this comprehensive review will focus on the energy conversion, transformation kinetics and electron transfer of the ORR process as catalyzed by Fe-N-C catalysts. And by taking these and other relevant analytical results for Fe-N-C materials into consideration, primary strategies in the improvement in Fe-N-C catalyst activity will be presented.

Full-text：https://link.springer.com/article/10.1007/s41918-019-00030-w/fulltext.html

关键词: Fe-N-C, Oxygen reduction reaction, Mechanism, Characterization, Activity improvement

Abstract: Currently, Fe-N-C materials are considered to be among the most important oxygen reduction reaction (ORR) catalysts, because they are potential substitutes for Pt-based catalysts and are therefore promising in the development of non-noble metal-based catalysts. However, challenges such as electron transfer kinetics still exist and need to be improved upon. From a chemical stand point, improvements can be made through the better understanding of mechanisms in Fe-N-C-based ORR catalysis along with a deeper understanding of the chemical origin of active sites on Fe-N-C catalyst surfaces. Based on these, this comprehensive review will focus on the energy conversion, transformation kinetics and electron transfer of the ORR process as catalyzed by Fe-N-C catalysts. And by taking these and other relevant analytical results for Fe-N-C materials into consideration, primary strategies in the improvement in Fe-N-C catalyst activity will be presented.

Full-text：https://link.springer.com/article/10.1007/s41918-019-00030-w/fulltext.html

Key words: Fe-N-C, Oxygen reduction reaction, Mechanism, Characterization, Activity improvement

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