Porous Organic Framework-Based Materials (MOFs, COFs and HOFs) for Lithium-/Sodium-/Potassium-/Zinc-/Aluminum-/Calcium-Ion Batteries: A Review

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  • 1. School of Materials Science and Engineering, Institute for New Energy Materials and Engineering, Fuzhou University, Fuzhou 350108, Fujian, China;
    2. Fujian Engineering Research Center of High Energy Batteries and New Energy Equipment and Systems, Fuzhou University, Fuzhou 350108, Fujian, China

Received date: 2024-11-10

  Revised date: 2024-12-05

  Online published: 2025-03-29

Supported by

The authors acknowledge the support of Sichuan Aizhong Comprehensive Energy Technology Service Co., Ltd. and Shenzhen Zhaoqing Leoch Battery Technology Co. Ltd.

Abstract

Porous organic frameworks (POFs), including metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded frameworks (HOFs), have become research and development hotspots in the field of metal-ion batteries (MIBs) because of their unique structures, variable pore sizes, high specific surface areas, abundant active sites and customizable frameworks. These natural advantages of POF materials provide sufficient conditions for high-performance electrode materials for MIBs. However, some POF-based materials are still in the early stages of development, and more efforts are needed to make them competitive in practical applications. This updated review provides a comprehensive overview of recent advancements in the application of POF-based materials for MIBs, including lithium-ion, sodium-ion, potassium-ion, zinc-ion, aluminum-ion and calcium-ion batteries. In addition, advanced characterization technologies and computational simulation techniques, including machine learning, are reviewed. The main challenges and prospects of the application of POF-based materials in MIBs are briefly discussed, which can provide insights into the design and synthesis of high-performance electrode materials.

Cite this article

Hui Zheng, Wei Yan, Jiujun Zhang . Porous Organic Framework-Based Materials (MOFs, COFs and HOFs) for Lithium-/Sodium-/Potassium-/Zinc-/Aluminum-/Calcium-Ion Batteries: A Review[J]. Electrochemical Energy Reviews, 2025 , 8(1) : 3 . DOI: 10.1007/s41918-025-00239-y

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