Hydrogen Generation and Storage

    Hydrogen Generation and Storage

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    Recent Progresses in Electrocatalysts for Water Electrolysis
    Muhammad Arif Khan, Hongbin Zhao, Wenwen Zou, Zhe Chen, Wenjuan Cao, Jianhui Fang, Jiaqiang Xu, Lei Zhang, Jiujun Zhang
    Electrochemical Energy Reviews    2018, 1 (4): 483-530.   DOI: 10.1007/s41918-018-0014-z
    Abstract18575)      PDF       Save
    The study of hydrogen evolution reaction and oxygen evolution reaction electrocatalysts for water electrolysis is a developing feld in which noble metal-based materials are commonly used. However, the associated high cost and low abundance of noble metals limit their practical application. Non-noble metal catalysts, aside from being inexpensive, highly abundant and environmental friendly, can possess high electrical conductivity, good structural tunability and comparable electrocatalytic performances to state-of-the-art noble metals, particularly in alkaline media, making them desirable candidates to reduce or replace noble metals as promising electrocatalysts for water electrolysis. This article will review and provide an overview of the fundamental knowledge related to water electrolysis with a focus on the development and progress of non-noble metal-based electrocatalysts in alkaline, polymer exchange membrane and solid oxide electrolysis. A critical analysis of the various catalysts currently available is also provided with discussions on current challenges and future perspectives. In addition, to facilitate future research and development, several possible research directions to overcome these challenges are provided in this article.

    Full-text:https://link.springer.com/article/10.1007/s41918-018-0014-z
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    Metal–Organic Frameworks (MOFs) and MOF-Derived Materials for Energy Storage and Conversion
    Xu Zhang, An Chen, Ming Zhong, Zihe Zhang, Xin Zhang, Zhen Zhou, Xian-He Bu
    Electrochemical Energy Reviews    2019, 2 (1): 29-104.   DOI: 10.1007/s41918-018-0024-x
    Abstract972)      PDF       Save
    As modern society develops, the need for clean energy becomes increasingly important on a global scale. Because of this, the exploration of novel materials for energy storage and utilization is urgently needed to achieve low-carbon economy and sustainable development. Among these novel materials, metal-organic frameworks (MOFs), a class of porous materials, have gained increasing attention for utilization in energy storage and conversion systems because of ultra-high surface areas, controllable structures, large pore volumes and tunable porosities. In addition to pristine MOFs, MOF derivatives such as porous carbons and nanostructured metal oxides can also exhibit promising performances in energy storage and conversion applications. In this review, the latest progress and breakthrough in the application of MOF and MOF-derived materials for energy storage and conversion devices are summarized, including Li-based batteries (Li-ion, Li-S and Li-O2 batteries), Na-ion batteries, supercapacitors, solar cells and fuel cells.

    Full-text:https://link.springer.com/article/10.1007/s41918-018-0024-x
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    The Hydrogen Oxidation Reaction in Alkaline Medium: An Overview
    Carlos Augusto Campos-Roldán, Nicolas Alonso-Vante
    Electrochemical Energy Reviews    2019, 2 (2): 312-331.   DOI: 10.1007/s41918-019-00034-6
    Abstract819)      PDF       Save
    The recent advances in electrocatalysis for the hydrogen evolution reactions in acid and alkaline media are carefully reviewed. In this sense, this short review focuses on precious and non-precious catalytic centers. The recent development of HOR electrocatalysts with novel structures and compositions is highlighted. The understandings of the correlation between the activity and the shape, size, composition, and synthesis methods are summarized. The research directions, e.g., on the further development of more active, more stable, and less expensive electrocatalysts for the anion-exchange membranes for the alkaline fuel cell technology are provided. In this context, positive perspectives to overcome the high kinetic barriers encountered in alkaline medium can be expected in the years to come.

    Full-text:https://link.springer.com/article/10.1007/s41918-019-00034-6/fulltext.html
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