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    Advanced Catalyst Design Strategies and In-Situ Characterization Techniques for Enhancing Electrocatalytic Activity and Stability of Oxygen Evolution Reaction
    Cejun Hu, Yanfang Hu, Bowen Zhang, Hongwei Zhang, Xiaojun Bao, Jiujun Zhang, Pei Yuan
    Electrochemical Energy Reviews    2024, 7 (3): 19-.   DOI: 10.1007/s41918-024-00219-8
    Abstract453)      PDF       Save
    Water electrolysis for hydrogen production holds great promise as an energy conversion technology. The electrolysis process contains two necessary electrocatalytic reactions, one is the hydrogen evolution reaction (HER) at the cathode, and the other is the oxygen evolution reaction (OER) at the anode. In general, the kinetics of OER is much slower than that of HER, dominating the overall of performance electrolysis. As identified, the slow kinetics of catalytic OER is mainly resulted from multiple electron transfer steps, and the catalysts often undergo compositional, structural, and electronic changes during operation, leading to complicated dynamic reaction mechanisms which have not been fully understood. Obviously, this challenge presents formidable obstacles to the development of highly efficient OER electrocatalysts. To address the issue, it is crucial to unravel the origins of intrinsic OER activity and stability and elucidate the catalytic mechanisms across diverse catalyst materials. In this context, in-situ/operando characterization techniques would play a pivotal role in understanding the catalytic reaction mechanisms by enabling real-time monitoring of catalyst structures under operational conditions. These techniques can facilitate the identification of active sites for OER and provide essential insights into the types and quantities of key reaction intermediates. This comprehensive review explores various catalyst design and synthesis strategies aimed at enhancing the intrinsic OER activity and stability of catalysts and examines the application of advanced in-situ/operando techniques for probing catalyst mechanisms during the OER process. Furthermore, the imperative need for developing innovative in-situ/operando techniques, theoretical artificial intelligence and machine learning and conducting theoretical research to better understand catalyst structural evolution under conditions closely resembling practical OER working states is also deeply discussed. Those efforts should be able to lay the foundation for the improved fabrication of practical OER catalysts.
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    Nanoporous Carbon Materials Derived from Biomass Precursors: Sustainable Materials for Energy Conversion and Storage
    Zhikai Chen, Xiaoli Jiang, Yash Boyjoo, Lan Zhang, Wei Li, Lin Zhao, Yanxia Liu, Yagang Zhang, Jian Liu, Xifei Li
    Electrochemical Energy Reviews    2024, 7 (3): 26-.   DOI: 10.1007/s41918-024-00223-y
    Abstract173)      PDF       Save
    Biomass, which is derived from abundant renewable resources, is a promising alternative to fossil-fuel-based carbon materials for building a green and sustainable society. Biomass-based carbon materials (BCMs) with tailored hierarchical pore structures, large specific surface areas, and various surface functional groups have been extensively studied as energy and catalysis-related materials. This review provides insights from the perspectives of intrinsic physicochemical properties and structure-property relationships for discussing several fundamental yet significant issues in BCMs and their consequences. First, the synthesis, properties, and influencing factors of BCMs are discussed. Then, the causes and effects of the poor mechanical properties of biochar are explored. The factors affecting the properties of BCMs are presented, and the approaches for tuning these properties of biochar are summarized. Further, the applications of BCMs in energy storage and conversion are highlighted, including hydrogen storage and production, fuel cells, supercapacitors, hybrid electrodes, catalytic reforming, oxygen and CO2 reduction, and acetylene hydrochlorination. Finally, the future trends and prospects for biochar are proposed. This review aims to serve as a useful, up-to-date reference for future studies on BCMs for energy and catalytic applications.
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    Perovskite Oxides Toward Oxygen Evolution Reaction: Intellectual Design Strategies, Properties and Perspectives
    Lin Bo Liu, Chenxing Yi, Hong Cheng Mi, Song Lin Zhang, Xian Zhu Fu, Jing Li Luo, Subiao Liu
    Electrochemical Energy Reviews    2024, 7 (2): 14-.   DOI: 10.1007/s41918-023-00209-2
    Abstract148)      PDF       Save
    Developing electrochemical energy storage and conversion devices (e.g., water splitting, regenerative fuel cells and rechargeable metal-air batteries) driven by intermittent renewable energy sources holds a great potential to facilitate global energy transition and alleviate the associated environmental issues. However, the involved kinetically sluggish oxygen evolution reaction (OER) severely limits the entire reaction efficiency, thus designing high-performance materials toward efficient OER is of prime significance to remove this obstacle. Among various materials, cost-effective perovskite oxides have drawn particular attention due to their desirable catalytic activity, excellent stability and large reserves. To date, substantial efforts have been dedicated with varying degrees of success to promoting OER on perovskite oxides, which have generated multiple reviews from various perspectives, e.g., electronic structure modulation and heteroatom doping and various applications. Nonetheless, the reviews that comprehensively and systematically focus on the latest intellectual design strategies of perovskite oxides toward efficient OER are quite limited. To bridge the gap, this review thus emphatically concentrates on this very topic with broader coverages, more comparative discussions and deeper insights into the synthetic modulation, doping, surface engineering, structure mutation and hybrids. More specifically, this review elucidates, in details, the underlying causality between the being-tuned physiochemical properties [e.g., electronic structure, metal-oxygen (M-O) bonding configuration, adsorption capacity of oxygenated species and electrical conductivity] of the intellectually designed perovskite oxides and the resulting OER performances, coupled with perspectives and potential challenges on future research. It is our sincere hope for this review to provide the scientific community with more insights for developing advanced perovskite oxides with high OER catalytic efficiency and further stimulate more exciting applications.
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    Two-Dimensional Mesoporous Materials for Energy Storage and Conversion: Current Status, Chemical Synthesis and Challenging Perspectives
    Jieqiong Qin, Zhi Yang, Feifei Xing, Liangzhu Zhang, Hongtao Zhang, Zhong-Shuai Wu
    Electrochemical Energy Reviews    2023, 6 (1): 9-.   DOI: 10.1007/s41918-022-00177-z
    Abstract490)      PDF       Save
    Two-dimensional (2D) mesoporous materials (2DMMs), defined as 2D nanosheets with randomly dispersed or orderly aligned mesopores of 2–50 nm, can synergistically combine the fascinating merits of 2D materials and mesoporous materials, while overcoming their intrinsic shortcomings, e.g., easy self-stacking of 2D materials and long ion transport paths in bulk mesoporous materials. These unique features enable fast ion diffusion, large specific surface area, and enriched adsorption/reaction sites, thus offering a promising solution for designing high-performance electrode/catalyst materials for next-generation energy storage and conversion devices (ESCDs). Herein, we review recent advances of state-of-the-art 2DMMs for high-efficiency ESCDs, focusing on two different configurations of in-plane mesoporous nanosheets and sandwich-like mesoporous heterostructures. Firstly, a brief introduction is given to highlighting the structural advantages (e.g., tailored chemical composition, sheet configuration, and mesopore geometry) and key roles (e.g., active materials and functional additives) of 2DMMs for high-performance ESCDs. Secondly, the chemical synthesis strategies of 2DMMs are summarized, including template-free, 2D-template, mesopore-template, and 2D mesopore dual-template methods. Thirdly, the wide applications of 2DMMs in advanced supercapacitors, rechargeable batteries, and electrocatalysis are discussed, enlightening their intrinsic structure–property relationships. Finally, the future challenges and perspectives of 2DMMs in energy-related fields are presented.In this review, the recent advances of 2DMMs (including in-plane mesoporous nanosheets and sandwich-like mesoporous heterostructures) for energy storage and conversion are systematically summarized.
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    Recent Advances and Perspectives of Electrochemical CO2 Reduction Toward C2+ Products on Cu-Based Catalysts
    Xiaodeng Wang, Qi Hu, Guodong Li, Hengpan Yang, Chuanxin He
    Electrochemical Energy Reviews    2022, 5 (S2): 28-.   DOI: 10.1007/s41918-022-00171-5
    Abstract420)      PDF       Save
    Renewable-electricity-powered electrochemical CO2 reduction reactions (CO2RR) to highly value-added multi-carbon (C2+) fuels or chemicals have been widely recognized as a promising approach for achieving carbon recycling and thus bringing about sustainable environmental and economic benefits. Cu-based catalysts have been demonstrated as the only candidate metal CO2RR electrocatalysts that catalyze the C-C coupling. Unfortunately, huge challenges still exist in the highly selective CO2RR to C2+ products due to the higher activation barrier of C-C coupling and complex multi-electron reaction. Key fundamental issues regarding both active species and product formation pathways have not been elucidated by now, but recent developments of advanced strategies and characterization tools allow one to comprehensively understand the Cu-based CO2RR mechanism. Herein, we review recent advance and perspective of Cu-based CO2RR catalysts, especially in terms of active phases and product formation pathways. Then, strategies in catalysts design for CO2RR toward C2+ products are also presented. Importantly, we systematically summarized the advanced tools for investigating the CO2RR mechanism, including in situ/operando spectroscopy techniques, isotope labeling, and theoretical calculations, aiming at unifying the knowledge of active species and product formation pathways. Finally, future challenges and constructive perspectives are discussed, facilitating the accelerated advancement of CO2RR mechanism research.
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    Self-Supported Graphene Nanosheet-Based Composites as Binder-Free Electrodes for Advanced Electrochemical Energy Conversion and Storage
    Bowen Ren, Hao Cui, Chengxin Wang
    Electrochemical Energy Reviews    2022, 5 (S2): 32-.   DOI: 10.1007/s41918-022-00138-6
    Abstract781)      PDF       Save
    Graphene is composed of single-layered sp2 graphite and has been widely used in electrochemical energy conversion and storage due to its appealing physical and chemical properties. In recent years, a new kind of the self-supported graphene nanosheet-based composite (GNBC) has attracted significant attention. Compared with conventional powdered materials, a binder-free electrode architecture has several strengths, including a large surface area, enhanced reaction kinetics, and great structural stability, and these strengths allow users to realize the full potential of graphene. Based on these findings, this review presents preparation strategies and properties of self-supported GNBCs. Additionally, it highlights recent significant developments with integrated binder-free electrodes for several practical applications, such as lithium-ion batteries, lithium-metal batteries, supercapacitors, water splitting and metal-air batteries. In addition, the remaining challenges and future perspectives in this emerging field are also discussed.
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    Rational Design of Atomic Site Catalysts for Electrocatalytic Nitrogen Reduction Reaction: One Step Closer to Optimum Activity and Selectivity
    Yiran Ying, Ke Fan, Jinli Qiao, Haitao Huang
    Electrochemical Energy Reviews    2022, 5 (3): 6-.   DOI: 10.1007/s41918-022-00164-4
    Abstract2166)      PDF       Save
    The electrocatalytic nitrogen reduction reaction (NRR) has been one of the most intriguing catalytic reactions in recent years, providing an energy-saving and environmentally friendly alternative to the conventional Haber-Bosch process for ammonia production. However, the activity and selectivity issues originating from the activation barrier of the NRR intermediates and the competing hydrogen evolution reaction result in the unsatisfactory NH3 yield rate and Faradaic efficiency of current NRR catalysts. Atomic site catalysts (ASCs), an emerging group of heterogeneous catalysts with a high atomic utilization rate, selectivity, and stability, may provide a solution. This article undertakes an exploration and systematic review of a highly significant research area:the principles of designing ASCs for the NRR. Both the theoretical and experimental progress and state-of-the-art techniques in the rational design of ASCs for the NRR are summarized, and the topic is extended to double-atom catalysts and boron-based metal-free ASCs. This review provides guidelines for the rational design of ASCs for the optimum activity and selectivity for the electrocatalytic NRR.
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    Advanced Strategies for Stabilizing Single-Atom Catalysts for Energy Storage and Conversion
    Wenxian Li, Zehao Guo, Jack Yang, Ying Li, Xueliang Sun, Haiyong He, Sean Li, Jiujun Zhang
    Electrochemical Energy Reviews    2022, 5 (3): 9-.   DOI: 10.1007/s41918-022-00169-z
    Abstract437)      PDF       Save
    Well-defined atomically dispersed metal catalysts (or single-atom catalysts) have been widely studied to fundamentally understand their catalytic mechanisms, improve the catalytic efficiency, increase the abundance of active components, enhance the catalyst utilization, and develop cost-effective catalysts to effectively reduce the usage of noble metals. Such single-atom catalysts have relatively higher selectivity and catalytic activity with maximum atom utilization due to their unique characteristics of high metal dispersion and a low-coordination environment. However, freestanding single atoms are thermodynamically unstable, such that during synthesis and catalytic reactions, they inevitably tend to agglomerate to reduce the system energy associated with their large surface areas. Therefore, developing innovative strategies to stabilize single-atom catalysts, including mass-separated soft landing, one-pot pyrolysis, co-precipitation, impregnation, atomic layer deposition, and organometallic complexation, is critically needed. Many types of supporting materials, including polymers, have been commonly used to stabilize single atoms in these fabrication techniques. Herein, we review the stabilization strategies of single-atom catalyst, including different synthesis methods, specific metals and carriers, specific catalytic reactions, and their advantages and disadvantages. In particular, this review focuses on the application of polymers in the synthesis and stabilization of single-atom catalysts, including their functions as carriers for metal single atoms, synthetic templates, encapsulation agents, and protection agents during the fabrication process. The technical challenges that are currently faced by single-atom catalysts are summarized, and perspectives related to future research directions including catalytic mechanisms, enhancement of the catalyst loading content, and large-scale implementation are proposed to realize their practical applications.
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    Electrospun Materials for Batteries Moving Beyond Lithium-Ion Technologies
    Jie Wang, Zhenzhu Wang, Jiangfeng Ni, Liang Li
    Electrochemical Energy Reviews    2022, 5 (2): 211-241.   DOI: 10.1007/s41918-021-00103-9
    Abstract3365)      PDF       Save
    Innovation and optimization have shifted battery technologies beyond the use of lithium ions and fostered the demand for enhanced materials, which are vital factors determining the energy, power, durability, and safety of systems. Current battery materials vary in their sizes, shapes, and morphology, and these have yet to meet the performance standards necessary to prevent deterioration in regard to the efficiency and reliability of beyond-lithium technologies. As a versatile and feasible technique for producing ultrathin fibers, electrospinning has been extensively developed to fabricate and engineer nanofibers of functional materials for battery applications. In this review, the basic concepts and characteristics of beyond-lithium batteries are expounded, and the fundamentals of electrospinning are reviewed. The aim is to provide a guide to researchers going into this field. Focuses are placed on how electrospinning can address some of the key technical challenges facing beyond-lithium technologies. We hope the knowledge presented in this work will stimulate the design of electrospun materials for future battery applications.
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    MOF/PCP-based Electrocatalysts for the Oxygen Reduction Reaction
    Liang Tang, Qinshang Xu, Yu Zhang, Wenqian Chen, Minghong Wu
    Electrochemical Energy Reviews    2022, 5 (1): 32-81.   DOI: 10.1007/s41918-021-00113-7
    Abstract2354)      PDF       Save
    Electrocatalysis|Oxygen reduction reaction|Metal-organic framework|Active sites|Dimension
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    Single-Atom Catalysts: Advances and Challenges in Metal-Support Interactions for Enhanced Electrocatalysis
    Yang Mu, Tingting Wang, Jian Zhang, Changgong Meng, Yifu Zhang, Zongkui Kou
    Electrochemical Energy Reviews    2022, 5 (1): 145-186.   DOI: 10.1007/s41918-021-00124-4
    Abstract2422)      PDF       Save
    Metal-support interaction|Single-atom catalysts|Electrocatalysis|ORR and OER|HER and HOR
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    1T Phase Transition Metal Dichalcogenides for Hydrogen Evolution Reaction
    Liang Chang, Zhuxing Sun, Yun Hang Hu
    Electrochemical Energy Reviews    2021, 4 (2): 194-218.   DOI: 10.1007/s41918-020-00087-y
    Abstract5478)      PDF       Save
    Metallic (1T) phases of transition metal dichalcogenides (TMDs) are promising alternatives for Pt as efficient and practically applicable hydrogen evolution reaction (HER) catalysts. Group 6 1T TMDs are the most widely studied due to their impressively higher HER activity than that of their 2H counterparts. However, the mediocre electrochemical and thermal stability of these TMDs has limited their widespread application. Over the last decade, while immense attempts have been made to enhance the stability of group 6 1T TMDs, 1T TMDs based on other transition metals have gained increasing attention. To address the great potential of the 1T TMD family for industry-scale HER and inspire future breakthroughs in realizing their scalable utilization, a critical overview of 1T TMDs for application in HER is presented in this work. With an emphasis on the recent progress, the main contents include the elucidation of the “structure–performance” relationship in 1T TMD-based HER, the approaches for the synthesis and morphology control of 1T TMDs, and the types of 1T TMD-based materials that have been explored for efficient and long-term water splitting. Before the main discussions, the reaction mechanism of HER and the evaluation indexes for HER catalysts are introduced. Moreover, future perspectives on overcoming the primary challenges that hinder the practical application of 1T TMDs for HER are provided.

    Full-text: https://link.springer.com/article/10.1007/s41918-020-00087-y
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    Application of Scanning Tunneling Microscopy in Electrocatalysis and Electrochemistry
    Haifeng Feng, Xun Xu, Yi Du, Shi Xue Dou
    Electrochemical Energy Reviews    2021, 4 (2): 249-268.   DOI: 10.1007/s41918-020-00074-3
    Abstract5188)      PDF       Save
    Scanning tunneling microscopy (STM) has gained increasing attention in the field of electrocatalysis due to its ability to reveal electrocatalyst surface structures down to the atomic level in either ultra-high-vacuum (UHV) or harsh electrochemical conditions. The detailed knowledge of surface structures, surface electronic structures, surface active sites as well as the interaction between surface adsorbates and electrocatalysts is highly beneficial in the study of electrocatalytic mechanisms and for the rational design of electrocatalysts. Based on this, this review will discuss the application of STM in the characterization of electrocatalyst surfaces and the investigation of electrochemical interfaces between electrocatalyst surfaces and reactants. Based on different operating conditions, UHV-STM and STM in electrochemical environments (EC-STM) are discussed separately. This review will also present emerging techniques including high-speed EC-STM, scanning noise microscopy and tip-enhanced Raman spectroscopy.

    Full-text: https://link.springer.com/article/10.1007/s41918-020-00074-3
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    A Review of Composite/Hybrid Electrocatalysts and Photocatalysts for Nitrogen Reduction Reactions: Advanced Materials, Mechanisms, Challenges and Perspectives
    Revanasiddappa Manjunatha, Aleksandar Karajić, Minmin Liu, Zibo Zhai, Li Dong, Wei Yan, David P. Wilkinson, Jiujun Zhang
    Electrochemical Energy Reviews    2020, 3 (3): 506-540.   DOI: 10.1007/s41918-020-00069-0
    Abstract464)      PDF       Save

    The electrochemical reduction of nitrogen to produce ammonia using sustainable and “green” materials and electricity has proven to be not only feasible, but promising. However, low catalytic activity and stability as well as poor product selectivity have hindered practical application. To address this, this review will provide a comprehensive presentation of the latest progress in the experimental investigation and fundamental understanding of nitrogen reduction reaction (NRR) for the production of ammonia as catalyzed by electrocatalysts and photocatalysts. In particular, the design, synthesis, characterization and performance validation of these catalysts are classified and analyzed in terms of their catalytic activity, stability and selectivity toward ammonia production. Reviewed electrocatalysts include metal/carbon, metal/metal oxide and metal oxide/carbon composites, and reviewed photocatalysts include semiconductor-semiconductor, semiconductor-metal, semiconductor-carbon and multicomponent heterojunctions. Furthermore, several challenges are discussed and possible research directions are proposed to facilitate further research and development to overcome the challenges in NRR toward practical application.


    Full-text:https://link.springer.com/article/10.1007/s41918-020-00069-0

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    Graphene for Energy Storage and Conversion: Synthesis and Interdisciplinary Applications
    Liqi Bai, Yihe Zhang, Wangshu Tong, Li Sun, Hongwei Huang, Qi An, Na Tian, Paul K. Chu
    Electrochemical Energy Reviews    2020, 3 (2): 395-430.   DOI: 10.1007/s41918-019-00042-6
    Abstract1692)      PDF       Save

    2D graphene materials possess excellent electrical conductivity and an sp2 carbon atom structure and can be applied in light and electric energy storage and conversion applications. However, traditional methods of graphene preparation cannot keep pace with real-time synthesis, and therefore, novel graphene synthesis approaches have attracted increasing attention from researchers to accurately control graphene structure and morphology. Based on this, this review will discuss the novel synthesis of graphene for interdisciplinary applications of energy storage and conversion, which is a promising direction in the research for novel applications in photoelectrochemical cells, photo-assisted batteries, piezoelectric nanogenerators, photothermal and photomechanical devices, etc.


    Full-text:https://link.springer.com/article/10.1007/s41918-019-00042-6

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    Materials and Fabrication Methods for Electrochemical Supercapacitors: Overview
    Prasad Eknath Lokhande, Umesh S. Chavan, Abhishek Pandey
    Electrochemical Energy Reviews    2020, 3 (1): 155-186.   DOI: 10.1007/s41918-019-00057-z
    Abstract584)      PDF       Save

    The rapid economic development and immense growth in the portable electronic market create tremendous demand for clean energy sources and energy storage and conversion technologies. To meet this demand, supercapacitors have emerged as a promising technology to store renewable energy resources. Based on this, this review will provide a detailed and current overview of the various materials explored as potential electrodes and electrolytes in the development of efficient supercapacitors along with corresponding synthesis routes and electrochemical properties. In addition, this review will provide introductions into the various types of supercapacitors as well as fundamental parameters that affect supercapacitor performance. Finally, this review will conclude with presentations on the role of electrolytes in supercapacitors and corresponding materials along with challenges and perspectives to guide future development.


    Full-text:https://link.springer.com/article/10.1007/s41918-019-00057-z

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    One-Pot Seedless Aqueous Design of Metal Nanostructures for Energy Electrocatalytic Applications
    Jianping Lai, Yuguang Chao, Peng Zhou, Yong Yang, Yelong Zhang, Wenxiu Yang, Dong Wu, Jianrui Feng, Shaojun Guo
    Electrochemical Energy Reviews    2018, 1 (4): 531-547.   DOI: 10.1007/s41918-018-0018-8
    Abstract18904)      PDF       Save
    Over the past several decades, extensive eforts have been undertaken to fnd methods to synthesize advanced electrocatalysts that possess rationally controllable sizes, shapes, crystallinities, compositions and structures for efcient energy conversion technologies. Of these methods, the one-pot seedless synthetic method in aqueous solution at ambient temperature has attracted extensive attention from researchers because it is a simple, inexpensive, energy-efcient, safe and less toxic method for the synthesis of electrocatalytic nanomaterials. In this review, recent developments in one-pot seedless synthetic strategies for the design of various structures of Au, Pt, Pd, Ag and multimetallic nanocrystals in aqueous solutions at ambient temperatures will be introduced, primarily focusing on the structure-electrocatalytic performance relationships of the as-prepared metal nanocrystals. Current challenges and outlooks for future research directions will also be provided in this promising research feld.

    Full-text:https://link.springer.com/article/10.1007/s41918-018-0018-8
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    Engineering Graphenes from the Nano- to the Macroscale for Electrochemical Energy Storage
    Junwei Han, Wei Wei, Chen Zhang, Ying Tao, Wei Lv, Guowei Ling, Feiyu Kang, Quan-Hong Yang
    Electrochemical Energy Reviews    2018, 1 (2): 139-168.   DOI: 10.1007/s41918-018-0006-z
    Abstract2649)      PDF       Save
    Carbon is a key component in current electrochemical energy storage (EES) devices and plays a crucial role in the improvement in energy and power densities for the future EES devices. As the simplest carbon and the basic unit of all sp2 carbons, graphene is widely used in EES devices because of its fascinating and outstanding physicochemical properties; however, when assembled in the macroscale, graphene-derived materials do not demonstrate their excellence as individual sheets mostly because of unavoidable stacking. This review proposal shows to engineer graphene nanosheets from the nano- to the macroscale in a well-designed and controllable way and discusses how the performance of the graphene-derived carbons depends on the individual graphene sheets, nanostructures, and macrotextures. Graphene-derived carbons in EES applications are comprehensively reviewed with three representative devices, supercapacitors, lithium-ion batteries, and lithium-sulfur batteries. The review concludes with a comment on the opportunities and challenges for graphene-derived carbons in the rapidly growing EES research area.

    Full-text:https://link.springer.com/article/10.1007/s41918-018-0006-z
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    Cited: Baidu(5)
    Carbon-Based Metal-Free Electrocatalysis for Energy Conversion, Energy Storage, and Environmental Protection
    Chuangang Hu, Ying Xiao, Yuqin Zou, Liming Dai
    Electrochemical Energy Reviews    2018, 1 (1): 84-112.   DOI: 10.1007/s41918-018-0003-2
    Abstract1019)      PDF       Save
    Carbon-based metal-free catalysts possess desirable properties such as high earth abundance, low cost, high electrical conductivity, structural tunability, good selectivity, strong stability in acidic/alkaline conditions, and environmental friendliness. Because of these properties, these catalysts have recently received increasing attention in energy and environmental applications. Subsequently, various carbon-based electrocatalysts have been developed to replace noble metal catalysts for low-cost renewable generation and storage of clean energy and environmental protection through metal-free electrocatalysis. This article provides an up-to-date review of this rapidly developing feld by critically assessing recent advances in the mechanistic understanding, structure design, and material/device fabrication of metal-free carbon-based electrocatalysts for clean energy conversion/storage and environmental protection, along with discussions on current challenges and perspectives.

    Full-text: https://link.springer.com/article/10.1007/s41918-018-0003-2
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