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Table of Content

    20 November 2020, Volume 3 Issue 4
    Challenges and Development of Tin-Based Anode with High Volumetric Capacity for Li-Ion Batteries
    Fengxia Xin, M. Stanley Whittingham
    2020, 3(4):  643-655.  doi:10.1007/s41918-020-00082-3
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    The ever-increasing energy density needs for the mass deployment of electric vehicles bring challenges to batteries. Graphitic carbon must be replaced with a higher-capacity material for any significant advancement in the energy storage capability. Sn-based materials are strong candidates as the anode for the next-generation lithium-ion batteries due to their higher volumetric capacity and relatively low working potential. However, the volume change of Sn upon the Li insertion and extraction process results in a rapid deterioration in the capacity on cycling. Substantial effort has been made in the development of Sn-based materials. A SnCo alloy has been used, but is not economically viable. To minimize the use of Co, a series of Sn-Fe-C, SnyFe, Sn-C composites with excellent capacity retention and rate capability has been investigated. They show the proof of principle that alloys can achieve Coulombic efficiency of over 99.95% after the first few cycles. However, the initial Coulombic efficiency needs improvement. The development and application of tin-based materials in LIBs also provide useful guidelines for sodium-ion batteries, potassium-ion batteries, magnesium-ion batteries and calcium-ion batteries.


    Full-text: https://link.springer.com/article/10.1007/s41918-020-00082-3

    Comprehensive Investigation into Garnet Electrolytes Toward Application-Oriented Solid Lithium Batteries
    Mengyang Jia, Ning Zhao, Hanyu Huo, Xiangxin Guo
    2020, 3(4):  656-689.  doi:10.1007/s41918-020-00076-1
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    To satisfy the ever-increasing demand for higher energy density, solid-state batteries (SSBs) have received significant attention due to their potential in providing energy densities greater than 400 Wh kg-1. And as a key material in SSBs, the garnet-type Li7La3Zr2O12 (LLZO) electrolyte is particularly promising because of its high ionic conductivity at room temperature and excellent chemical stability against Li metal. And although great progress has been achieved for garnet electrolytes, many critical issues remain in terms of the practical application of garnet-based SSBs with truly high energy densities. Based on this, this review will provide an overview of the current progress in solid garnet batteries in terms of electrolyte fabrication and interfacial engineering in prototype cells. In addition, various strategies used to meet application requirements are comprehensively reviewed, including not only strategies to enhance energy density, but also methods to enhance rate capability, extend cycle life, decrease cost and reduce thermal runaways. Furthermore, crucial challenges are presented and future research directions are proposed in the development of high-performance solid lithium batteries.


    Full-text:https://link.springer.com/article/10.1007/s41918-020-00076-1

    Electrochemical Compression Technologies for High-Pressure Hydrogen: Current Status, Challenges and Perspective
    Jiexin Zou, Ning Han, Jiangyan Yan, Qi Feng, Yajun Wang, Zhiliang Zhao, Jiantao Fan, Lin Zeng, Hui Li, Haijiang Wang
    2020, 3(4):  690-729.  doi:10.1007/s41918-020-00077-0
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    Hydrogen is an ideal energy carrier in future applications due to clean byproducts and high efficiency. However, many challenges remain in the application of hydrogen, including hydrogen production, delivery, storage and conversion. In terms of hydrogen storage, two compression modes (mechanical and non-mechanical compressors) are generally used to increase volume density in which mechanical compressors with several classifications including reciprocating piston compressors, hydrogen diaphragm compressors and ionic liquid compressors produce significant noise and vibration and are expensive and inefficient. Alternatively, non-mechanical compressors are faced with issues involving large-volume requirements, slow reaction kinetics and the need for special thermal control systems, all of which limit large-scale development. As a result, modular, safe, inexpensive and efficient methods for hydrogen storage are urgently needed. And because electrochemical hydrogen compressors (EHCs) are modular, highly efficient and possess hydrogen purification functions with no moving parts, they are becoming increasingly prominent. Based on all of this and for the first time, this review will provide an overview of various hydrogen compression technologies and discuss corresponding structures, principles, advantages and limitations. This review will also comprehensively present the recent progress and existing issues of EHCs and future hydrogen compression techniques as well as corresponding containment membranes, catalysts, gas diffusion layers and flow fields. Furthermore, engineering perspectives are discussed to further enhance the performance of EHCs in terms of the thermal management, water management and the testing protocol of EHC stacks. Overall, the deeper understanding of potential relationships between performance and component design in EHCs as presented in this review can guide the future development of anticipated EHCs.


    Full-text:https://link.springer.com/article/10.1007/s41918-020-00077-0

    Surface Segregation in Solid Oxide Cell Oxygen Electrodes: Phenomena, Mitigation Strategies and Electrochemical Properties
    Kongfa Chen, San Ping Jiang
    2020, 3(4):  730-765.  doi:10.1007/s41918-020-00078-z
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    Solid oxide cells (SOCs) are highly efficient and environmentally benign devices that can be used to store renewable electrical energy in the form of fuels such as hydrogen in the solid oxide electrolysis cell mode and regenerate electrical power using stored fuels in the solid oxide fuel cell mode. Despite this, insufficient long-term durability over 5-10 years in terms of lifespan remains a critical issue in the development of reliable SOC technologies in which the surface segregation of cations, particularly strontium (Sr) on oxygen electrodes, plays a critical role in the surface chemistry of oxygen electrodes and is integral to the overall performance and durability of SOCs. Due to this, this review will provide a critical overview of the surface segregation phenomenon, including influential factors, driving forces, reactivity with volatile impurities such as chromium, boron, sulphur and carbon dioxide, interactions at electrode/electrolyte interfaces and influences on the electrochemical performance and stability of SOCs with an emphasis on Sr segregation in widely investigated (La,Sr)MnO3 and (La,Sr)(Co,Fe)O3-δ. In addition, this review will present strategies for the mitigation of Sr surface segregation.


    Full-text:https://link.springer.com/article/10.1007/s41918-020-00078-z

    Tailoring MXene-Based Materials for Sodium-Ion Storage: Synthesis, Mechanisms, and Applications
    Yao-Jie Lei, Zi-Chao Yan, Wei-Hong Lai, Shu-Lei Chou, Yun-Xiao Wang, Hua-Kun Liu, Shi-Xue Dou
    2020, 3(4):  766-792.  doi:10.1007/s41918-020-00079-y
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    Advanced electrodes with excellent rate performance and cycling stability are in demand for the fast development of sodium storage. Two-dimensional (2D) materials have emerged as one of the most investigated subcategories of sodium storage related anodes due to their superior electron transfer capability, mechanical flexibility, and large specific surface areas. Recently, 2D metal carbides and nitrides (MXenes), one type of the new 2D materials, are known to have competitive advantages in terms of high electroconductivity, terminal functional groups, large specific surface areas, tunable interlayer spacing, and remarkable safety. These advances endow MXenes and MXene-based materials with superior electrochemical performance when they are used as electrodes for sodium-ion storage. MXenes, however, share similar defects with other 2D materials, such as serious restacking and aggregation, which need to be improved in consideration of their further applications. In this review, we present the big family of MXenes and their synthetic methods. Furthermore, recent research reports related to progress on MXene-based materials for sodium storage are compiled, including materials design and reaction mechanisms in sodium-ion batteries and sodium metal batteries. Significantly, we discuss the challenges for existing MXene-based structures with respect to their future use as electrodes, such as low capacitance, aggregation, untenable termination groups, and unclear mechanisms, thereby providing guidance for future research on MXene-based materials for sodium-ion storage.


    Full-text:https://link.springer.com/article/10.1007/s41918-020-00079-y

    Polybenzimidazole-Based High-Temperature Polymer Electrolyte Membrane Fuel Cells: New Insights and Recent Progress
    David Aili, Dirk Henkensmeier, Santiago Martin, Bhupendra Singh, Yang Hu, Jens Oluf Jensen, Lars N. Cleemann, Qingfeng Li
    2020, 3(4):  793-845.  doi:10.1007/s41918-020-00080-5
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    High-temperature proton exchange membrane fuel cells based on phosphoric acid-doped polybenzimidazole membranes are a technology characterized by simplified construction and operation along with possible integration with, e.g., methanol reformers. Significant progress has been achieved in terms of key materials, components and systems. This review is devoted to updating new insights into the fundamental understanding and technological deployment of this technology. Polymers are synthetically modified with basic functionalities, and membranes are improved through cross-linking and inorganic-organic hybridization. New insights into phosphoric acid along with its interactions with basic polymers, metal catalysts and carbon-based supports are recapped. Recognition of parasitic acid migration raises acid retention issues at high current densities. Acid loss via evaporation is estimated with respect to the acid inventory of membrane electrode assembly. Acid adsorption on platinum surfaces can be alleviated for platinum alloys and non-precious metal catalysts. Binders have been considered a key to the establishment of the triple-phase boundary, while recent development of binderless electrodes opens new avenues toward low Pt loadings. Often ignored microporous layers and water impacts are also discussed. Of special concern are durability issues including acid loss, platinum sintering and carbon corrosion, the latter being critical during start/stop cycling with mitigation measures proposed. Long-term durability has been demonstrated with a voltage degradation rate of less than 1 μV h-1 under steady-state tests at 160℃, while challenges remain at higher temperatures, current densities or reactant stoichiometries, particularly during dynamic operation with thermal, load or start/stop cycling.


    Full-text:https://link.springer.com/article/10.1007/s41918-020-00080-5