Electrochemical Energy Reviews ›› 2022, Vol. 5 ›› Issue (1): 32-81.doi: 10.1007/s41918-021-00113-7

• • 上一篇    下一篇

MOF/PCP-based Electrocatalysts for the Oxygen Reduction Reaction

Liang Tang1,2, Qinshang Xu1,2, Yu Zhang1,2, Wenqian Chen1,2, Minghong Wu1,2   

  1. 1. Key Laboratory of Organic Compound Pollution Control Engineering, Ministry of Education, Shanghai, 200444, China;
    2. School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China
  • 收稿日期:2021-01-26 修回日期:2021-04-24 出版日期:2022-03-20 发布日期:2022-03-14
  • 通讯作者: Wenqian Chen,E-mail:wenqianchen@shu.edu.cn;Minghong Wu,E-mail:mhwu@shu.edu.cn E-mail:wenqianchen@shu.edu.cn;mhwu@shu.edu.cn
  • 基金资助:
    The authors of this work gratefully appreciate the financial support provided by the National Natural Science Foundation of China (Nos. 41573096, 21707064), Program for Changjiang Scholars and Innovative Research Team in University (No. IRT_17R71), and Program for the Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning (QD2019005).

MOF/PCP-based Electrocatalysts for the Oxygen Reduction Reaction

Liang Tang1,2, Qinshang Xu1,2, Yu Zhang1,2, Wenqian Chen1,2, Minghong Wu1,2   

  1. 1. Key Laboratory of Organic Compound Pollution Control Engineering, Ministry of Education, Shanghai, 200444, China;
    2. School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China
  • Received:2021-01-26 Revised:2021-04-24 Online:2022-03-20 Published:2022-03-14
  • Contact: Wenqian Chen,E-mail:wenqianchen@shu.edu.cn;Minghong Wu,E-mail:mhwu@shu.edu.cn E-mail:wenqianchen@shu.edu.cn;mhwu@shu.edu.cn
  • Supported by:
    The authors of this work gratefully appreciate the financial support provided by the National Natural Science Foundation of China (Nos. 41573096, 21707064), Program for Changjiang Scholars and Innovative Research Team in University (No. IRT_17R71), and Program for the Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning (QD2019005).

摘要: The oxygen reduction reaction (ORR) is the fundamental reaction at the cathode of a fuel cell. Although the commercial precious metal catalyst Pt/C has unique catalytic activity, its high cost, low storage capacity and poor stability limit the commercial application of fuel cells. Therefore, it is essential to explore catalysts with abundant functional materials and develop fuel cells with high activity and high stability. Metal-organic frameworks (MOFs) or porous coordination polymers (PCPs) are highly designable structures composed of organic ligands and metal ions. Because of their large specific surface area, high porosity and tunable chemical structure, MOFs/PCPs are considered the most promising catalytic material for the ORR. This review discusses the research progress and latest development of MOF/PCP applications as ORR catalysts, including the basic principles and the design rules of MOFs/PCPs as ORR catalysts. In addition, this work also elaborates on the active sites of ORR catalysts, which originate from the MOFs/PCPs. Ultimately, we present a research review of the last 5 years and the prospects in the field of using MOFs/PCPs for the fabrication of ORR catalysts.

关键词: Electrocatalysis, Oxygen reduction reaction, Metal-organic framework, Active sites, Dimension

Abstract: Electrocatalysis|Oxygen reduction reaction|Metal-organic framework|Active sites|Dimension