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Electrochemical Energy Reviews ›› 2023, Vol. 6 ›› Issue (4): 36-.doi: 10.1007/s41918-023-00199-1

• • 上一篇    下一篇

Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries

Sha Tan1, Zulipiya Shadike1,6, Xinyin Cai6, Ruoqian Lin1, Atsu Kludze2, Oleg Borodin3, Brett L. Lucht4, Chunsheng Wang5, Enyuan Hu1, Kang Xu3,7, Xiao-Qing Yang1   

  1. 1. Chemistry Division, Brookhaven National Laboratory, Upton, NY 11973, USA;
    2. Robert Frederick Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14850, USA;
    3. Battery Science Branch, Energy Science Division, Army Research Directorate, US Army Research Laboratory, Adelphi, MD 20783, USA;
    4. Department of Chemistry, University of Rhode Island, Kingston, RI 02881, USA;
    5. Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, MD 20740, USA;
    6. Institute of Fuel Cells, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;
    7. Present Address: SolidEnergy Systems, (SES), 35 Cabot Rd., Woburn, MA 01801, USA
  • 收稿日期:2022-05-06 修回日期:2022-10-17 出版日期:2023-12-20 发布日期:2023-12-28
  • 通讯作者: Zulipiya Shadike, E-mail:zshadike@sjtu.edu.cn;Enyuan Hu, E-mail:enhu@bnl.gov;Kang Xu, E-mail:kang.xu@ses.ai;Xiao?Qing Yang, E-mail:xyang@bnl.gov E-mail:zshadike@sjtu.edu.cn;enhu@bnl.gov;kang.xu@ses.ai;xyang@bnl.gov
  • 基金资助:
    This work was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technology Office of the U.S. DOE through Applied Battery Research for Transportation (ABRT) Program under contract No. DE-SC0012704. The work done at Shanghai Jiao Tong University was supported by Shanghai Pujiang Program (21PJ1408700).

Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries

Sha Tan1, Zulipiya Shadike1,6, Xinyin Cai6, Ruoqian Lin1, Atsu Kludze2, Oleg Borodin3, Brett L. Lucht4, Chunsheng Wang5, Enyuan Hu1, Kang Xu3,7, Xiao-Qing Yang1   

  1. 1. Chemistry Division, Brookhaven National Laboratory, Upton, NY 11973, USA;
    2. Robert Frederick Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14850, USA;
    3. Battery Science Branch, Energy Science Division, Army Research Directorate, US Army Research Laboratory, Adelphi, MD 20783, USA;
    4. Department of Chemistry, University of Rhode Island, Kingston, RI 02881, USA;
    5. Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, MD 20740, USA;
    6. Institute of Fuel Cells, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;
    7. Present Address: SolidEnergy Systems, (SES), 35 Cabot Rd., Woburn, MA 01801, USA
  • Received:2022-05-06 Revised:2022-10-17 Online:2023-12-20 Published:2023-12-28
  • Contact: Zulipiya Shadike, E-mail:zshadike@sjtu.edu.cn;Enyuan Hu, E-mail:enhu@bnl.gov;Kang Xu, E-mail:kang.xu@ses.ai;Xiao?Qing Yang, E-mail:xyang@bnl.gov E-mail:zshadike@sjtu.edu.cn;enhu@bnl.gov;kang.xu@ses.ai;xyang@bnl.gov
  • Supported by:
    This work was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technology Office of the U.S. DOE through Applied Battery Research for Transportation (ABRT) Program under contract No. DE-SC0012704. The work done at Shanghai Jiao Tong University was supported by Shanghai Pujiang Program (21PJ1408700).

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摘要： Among various rechargeable batteries, the lithium-ion battery (LIB) stands out due to its high energy density, long cycling life, in addition to other outstanding properties. However, the capacity of LIB drops dramatically at low temperatures (LTs) below 0 °C, thus restricting its applications as a reliable power source for electric vehicles in cold climates and equipment used in the aerospace. The electrolyte engineering has proved to be one of the most effective approaches to mitigate LIB performance degradation at LTs. In this review, we summarize the important factors contributing to the deterioration in Li+ transport and capacity utilization at LTs while systematically categorize the solvents, salts and additives reported in the literature. Strategies to improve the Li+ transport kinetics, in the bulk electrolyte and across the interphases, are discussed. In particular, the formation mechanism of solid electrolyte interphase and its functionality for LT electrolytes are analyzed. Perspectives on the future evolution of this area are also provided.

关键词: Electrolyte, Lithium battery, Low temperature, Solid electrolyte interphase, Ionic conductivity

Abstract: Among various rechargeable batteries, the lithium-ion battery (LIB) stands out due to its high energy density, long cycling life, in addition to other outstanding properties. However, the capacity of LIB drops dramatically at low temperatures (LTs) below 0 °C, thus restricting its applications as a reliable power source for electric vehicles in cold climates and equipment used in the aerospace. The electrolyte engineering has proved to be one of the most effective approaches to mitigate LIB performance degradation at LTs. In this review, we summarize the important factors contributing to the deterioration in Li+ transport and capacity utilization at LTs while systematically categorize the solvents, salts and additives reported in the literature. Strategies to improve the Li+ transport kinetics, in the bulk electrolyte and across the interphases, are discussed. In particular, the formation mechanism of solid electrolyte interphase and its functionality for LT electrolytes are analyzed. Perspectives on the future evolution of this area are also provided.

Key words: Electrolyte, Lithium battery, Low temperature, Solid electrolyte interphase, Ionic conductivity

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