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Electrochemical Energy Reviews ›› 2022, Vol. 5 ›› Issue (S2): 24-.doi: 10.1007/s41918-022-00161-7

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Atom Doping Engineering of Transition Metal Phosphides for Hydrogen Evolution Reactions

Huawei Bai1,2, Ding Chen1, Qianli Ma1, Rui Qin1, Hanwen Xu1, Yufeng Zhao3, Junxin Chen1, Shichun Mu1,2   

  1. 1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, Hubei, China;
    2. Foshan Xianhu Laboratory, Foshan, 528200, Guangdong, China;
    3. Institute for Sustainable Energy/College of Sciences, Shanghai University, Shanghai, 200444, China
  • 收稿日期:2021-11-18 修回日期:2022-02-04 出版日期:2022-12-20 发布日期:2023-02-11
  • 通讯作者: Shichun Mu,E-mail:msc@whut.edu.cn E-mail:msc@whut.edu.cn
  • 基金资助:
    Bai, H.W. and Chen, D. contributed equally. This work was supported by the National Natural Science Foundation of China (Grant No. 22075223), Shanghai Science and Technology Commission’s “2020 Science and Technology Innovation Action Plan” (20511104003), Wuhan University of Technology (CY202001) and the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technology) (2021-ZD-4).

Atom Doping Engineering of Transition Metal Phosphides for Hydrogen Evolution Reactions

Huawei Bai1,2, Ding Chen1, Qianli Ma1, Rui Qin1, Hanwen Xu1, Yufeng Zhao3, Junxin Chen1, Shichun Mu1,2   

  1. 1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, Hubei, China;
    2. Foshan Xianhu Laboratory, Foshan, 528200, Guangdong, China;
    3. Institute for Sustainable Energy/College of Sciences, Shanghai University, Shanghai, 200444, China
  • Received:2021-11-18 Revised:2022-02-04 Online:2022-12-20 Published:2023-02-11
  • Contact: Shichun Mu,E-mail:msc@whut.edu.cn E-mail:msc@whut.edu.cn
  • Supported by:
    Bai, H.W. and Chen, D. contributed equally. This work was supported by the National Natural Science Foundation of China (Grant No. 22075223), Shanghai Science and Technology Commission’s “2020 Science and Technology Innovation Action Plan” (20511104003), Wuhan University of Technology (CY202001) and the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technology) (2021-ZD-4).

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摘要： Transition metal phosphides (TMPs) have attracted attention in electrocatalytic hydrogen production because of their multiple active sites, adjustable structures, complex and variable composition, and distinctive electronic structures. However, the catalytic performance of pure TMPs in the hydrogen evolution reaction (HER) is not ideal. Fortunately, this situation can be changed by atom doping engineering because atom doping can efficaciously adjust the electronic structure, Gibbs free energy (ΔGH*) and d-band center to enhance the kinetics of catalytic reactions. Thus, atom doping engineering has aroused widespread interest. This review examines, analyzes and summarizes our previous work and that of others on atom doping engineering, including the activity origin of doped TMPs, doping with nonmetals (B, S, N, O, F, etc.), doping with metals (Ni, Co, Fe, Mn, Mo, Al, etc.) and codoping with nonmetals and metal atoms, as well as direct doping and synergetic doping, doping methods and the resulting HER properties. Finally, the key problems and future directions for development of atom doping in TMPs are discussed. This review will aid the design and construction of high-performance nonnoble metal catalysts for the HER and other electrocatalytic processes.

关键词: Transition metal phosphides, Electrocatalyst, Atom doping engineering, Hydrogen production, Hydrogen evolution reaction

Abstract: Transition metal phosphides (TMPs) have attracted attention in electrocatalytic hydrogen production because of their multiple active sites, adjustable structures, complex and variable composition, and distinctive electronic structures. However, the catalytic performance of pure TMPs in the hydrogen evolution reaction (HER) is not ideal. Fortunately, this situation can be changed by atom doping engineering because atom doping can efficaciously adjust the electronic structure, Gibbs free energy (ΔGH*) and d-band center to enhance the kinetics of catalytic reactions. Thus, atom doping engineering has aroused widespread interest. This review examines, analyzes and summarizes our previous work and that of others on atom doping engineering, including the activity origin of doped TMPs, doping with nonmetals (B, S, N, O, F, etc.), doping with metals (Ni, Co, Fe, Mn, Mo, Al, etc.) and codoping with nonmetals and metal atoms, as well as direct doping and synergetic doping, doping methods and the resulting HER properties. Finally, the key problems and future directions for development of atom doping in TMPs are discussed. This review will aid the design and construction of high-performance nonnoble metal catalysts for the HER and other electrocatalytic processes.

Key words: Transition metal phosphides, Electrocatalyst, Atom doping engineering, Hydrogen production, Hydrogen evolution reaction

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