Vanadium-Based Cathode Materials for Rechargeable Multivalent Batteries: Challenges and Opportunities

doi:10.1007/s41918-018-0007-y

Electrochemical Energy Reviews ›› 2018, Vol. 1 ›› Issue (2): 169-199.doi: 10.1007/s41918-018-0007-y

所属专题： Batteries

• REVIEW ARTICLE • 上一篇下一篇

Vanadium-Based Cathode Materials for Rechargeable Multivalent Batteries: Challenges and Opportunities

Han Tang, Zhuo Peng, Lu Wu, Fangyu Xiong, Cunyuan Pei, Qinyou An, Liqiang Mai

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China

收稿日期:2018-02-02 修回日期:2018-04-26 出版日期:2018-06-20 发布日期:2018-06-04
通讯作者: Qinyou An, Liqiang Mai E-mail:anqinyou86@whut.edu.cn;mlq518@whut.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (51602239, 51521001), the National Key Research and Development Program of China (2016YFA0202603, 2016YFA0202601), the National Basic Research Program of China (2013CB934103), the Programme of Introducing Talents of Discipline to Universities (B17034), the Hubei Provincial Natural Science Foundation of China (2016CFB267), the International Science and Technology Cooperation Program of China (2013DFA50840) and the Fundamental Research Funds for the Central Universities (WUT:2017Ⅲ009, 2017Ⅲ005).

Vanadium-Based Cathode Materials for Rechargeable Multivalent Batteries: Challenges and Opportunities

Han Tang, Zhuo Peng, Lu Wu, Fangyu Xiong, Cunyuan Pei, Qinyou An, Liqiang Mai

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China

Received:2018-02-02 Revised:2018-04-26 Online:2018-06-20 Published:2018-06-04
Contact: Qinyou An, Liqiang Mai E-mail:anqinyou86@whut.edu.cn;mlq518@whut.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (51602239, 51521001), the National Key Research and Development Program of China (2016YFA0202603, 2016YFA0202601), the National Basic Research Program of China (2013CB934103), the Programme of Introducing Talents of Discipline to Universities (B17034), the Hubei Provincial Natural Science Foundation of China (2016CFB267), the International Science and Technology Cooperation Program of China (2013DFA50840) and the Fundamental Research Funds for the Central Universities (WUT:2017Ⅲ009, 2017Ⅲ005).

摘要/Abstract

摘要： Due to the large reserves, low cost, high security and high energy density, rechargeable multivalent batteries have attracted extensive research enthusiasm for a long time. Multivalent batteries are also supposed as the potential candidates to Li-ion batteries in portable electronic devices and large-scale energy storage units. Unfortunately, most commercial cathode materials in Li-ion batteries cannot be applied in multivalent batteries because of the intensive polarization problem of multivalent intercalated ions (Mg²⁺, Zn²⁺, Al³⁺). Choosing and synthesizing the appropriate cathode materials are the main issues in overcoming the intensive polarization problem. Vanadium-based materials often possess many kinds of oxidation states because of the mutable vanadium element, which can facilitate achieving local electroneutrality and relieve the polarization problem of multivalent ions. In this review, we summarize the researches about the vanadium-based cathode materials for multivalent batteries and highlight the intercalation mechanism of multivalent ions to vanadium-based materials. In addition, diferent kinds of optimizing strategies are extracted from the literatures. On the basis of our review, progresses and future challenges of vanadium-based cathode materials in rechargeable multivalent batteries are more explicit.

Full-text：https://link.springer.com/article/10.1007/s41918-018-0007-y

关键词: Vanadium-based materials, Cathode materials, Rechargeable multivalent batteries, Energy storage

Abstract: Due to the large reserves, low cost, high security and high energy density, rechargeable multivalent batteries have attracted extensive research enthusiasm for a long time. Multivalent batteries are also supposed as the potential candidates to Li-ion batteries in portable electronic devices and large-scale energy storage units. Unfortunately, most commercial cathode materials in Li-ion batteries cannot be applied in multivalent batteries because of the intensive polarization problem of multivalent intercalated ions (Mg²⁺, Zn²⁺, Al³⁺). Choosing and synthesizing the appropriate cathode materials are the main issues in overcoming the intensive polarization problem. Vanadium-based materials often possess many kinds of oxidation states because of the mutable vanadium element, which can facilitate achieving local electroneutrality and relieve the polarization problem of multivalent ions. In this review, we summarize the researches about the vanadium-based cathode materials for multivalent batteries and highlight the intercalation mechanism of multivalent ions to vanadium-based materials. In addition, diferent kinds of optimizing strategies are extracted from the literatures. On the basis of our review, progresses and future challenges of vanadium-based cathode materials in rechargeable multivalent batteries are more explicit.

Full-text：https://link.springer.com/article/10.1007/s41918-018-0007-y

Key words: Vanadium-based materials, Cathode materials, Rechargeable multivalent batteries, Energy storage

Han Tang, Zhuo Peng, Lu Wu, Fangyu Xiong, Cunyuan Pei, Qinyou An, Liqiang Mai. Vanadium-Based Cathode Materials for Rechargeable Multivalent Batteries: Challenges and Opportunities[J]. Electrochemical Energy Reviews, 2018, 1(2): 169-199.

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Vanadium-Based Cathode Materials for Rechargeable Multivalent Batteries: Challenges and Opportunities

Vanadium-Based Cathode Materials for Rechargeable Multivalent Batteries: Challenges and Opportunities

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